The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Hypohalides+oxy acids of halogens / HOCl / IUPAC(2007)_298K_200-420nm(rec)

DATAFILE: HOCl_IUPAC(2007)_298K_200-420nm(rec).txt
NAME: hypochlorous acid
FORMULA: HOCl
AUTHOR(YEAR): IUPAC(2007)
T: 298K
λ: 200-420nm(rec)
BIBLIOGRAPHY: R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, and J. Troe, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume III - gas phase reactions of inorganic halogens", Atmos. Chem. Phys. 7, 981-1191 (2007); DOI: 10.5194/acp-7-981-2007
COMMENTS: IUPAC (2007) recommendation:

The preferred values of the absorption cross-sections at 298 K are the values calculated with the expression given by

R.J. Barnes, A. Sinha, and H.A. Michelsen, "Assessing the contribution of the lowest triplet state to the near-UV absorption spectrum of HOCl," J. Phys. Chem. A 102, 8855-8859 (1998); DOI: 10.1021/jp9835869,

based on their data from the laser induced fluorescence of HO and on the data of

J.B. Burkholder, "Ultraviolet absorption spectrum of HOCl," J. Geophys. Res. 98(D2), 2963-2974 (1993); DOI: 10.1029/92JD02522

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